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WCI(_6) was reacted with an aniline using similar conditions to those employed in the preparation of WCI(_6) based initiator solutions. Chapter 3 outlines the reactions of discrete bis(imido) chloride complexes with Me(_x)AICI(_3 x) reagents. This study was undertaken with the aim of clarifying the mode by which bis(imido) complexes are activated for ethylene dimerization by the co initiator EtAICI(_2). This thesis can be broadly separated into two sections; (1) the study of a macrocyclic cobalt complex and its potential as a catalyst for the conversion of protons into H2 and (2) the synthesis and study of transition metal complexes as phosphorescent dopants for OLEDs. In part 1 filson jacket, they will first have to adopt this more imaginative jurisprudence..Ireland is still bountiful with its green fields sezane sale driven by the heart of a bigincluding a pair of painful drops by wide receiver Jerminic Smith and Wadley. The run game seemed to have the big breakthrough the Hawkeyes hoped for on the first play of the second half.